Councillor Marion Atkinson said: "By working together, we can ensure the Local Skills Improvement Plan creates positive outcomes for our residents.”
The programme aims to boost access to work experience for young people facing barriers to employment.
The two organisations have signed an agreement to work together on activities to boost employability and skills among young people.
The Liverpool City Region Growth Plan aims to boost productivity, raise wages, and improve services for 1.6 million local residents.